Bj. Doleman et al., QUANTITATIVE STUDY OF THE RESOLVING POWER OF ARRAYS OF CARBON BLACK-POLYMER COMPOSITES IN VARIOUS VAPOR-SENSING TASKS, Analytical chemistry (Washington), 70(19), 1998, pp. 4177-4190
A statistical metric, based on the magnitude and standard deviations a
long linear projections of clustered away response data, was utilized
to facilitate an evaluation of the performance of detector arrays in v
arious vapor classification tasks. This approach allowed quantificatio
n of the ability of a 14-element array of carbon black-insulating poly
mer composite chemiresistors to distinguish between members of a set o
f 19 solvent vapors, some of which vary widely in chemical properties
(e.g., methanol and benzene) and others of which are very similar (e.g
., n-pentane and n-heptane). The data also facilitated evaluation of q
uestions such as the optimal number of detectors required for a specif
ic task, whether improved performance is obtained by increasing the nu
mber of detectors in a detector array, and how to assess statistically
the diversity of a collection of detectors in order 40 understand mor
e fully which properties are underrepresented in a particular set of a
rray elements. In addition, the resolving power of arrays of carbon bl
ack-polymer composites was compared to the resolving power of specific
collections of bulk conducting organic polymer or tin oxide detector
arrays in a common set of vapor classification tasks.