TRIMERIC BIS(CYCLOPENTADIENYL)OXOZIRCONIUM(IV) BENZENE SOLVATE

Authors
MIKHAILOVA OA MINACHEVA MH BURLAKOV VV SHUR VB PISAREVSKY AP YANOVSKY AI STRUCHKOV YT
Citation
Oa. Mikhailova et al., TRIMERIC BIS(CYCLOPENTADIENYL)OXOZIRCONIUM(IV) BENZENE SOLVATE, Acta crystallographica. Section C, Crystal structure communications, 49, 1993, pp. 1345-1347
Citations number
6
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
49
Year of publication
1993
Part
7
Pages
1345 - 1347
Database
ISI
SICI code
0108-2701(1993)49:<1345:TBBS>2.0.ZU;2-Y
Abstract
The title compound, -mu-oxo-tris[bis(eta5-cyclo-pentadienyl)zirconium] benzene solvate, obtained from the reaction of zirconocene hydride wi th CO2, is shown to contain planar Zr3O3 cycles with comparatively sho rt Zr-O distances [1.959 (5)-1.976 (5) angstrom] as a result of partia l double bonding.