STEREOSPECIFIC EPOXIDATION OF 2-HEXENE WITH MOLECULAR-OXYGEN ON PHOTOIRRADIATED TITANIUM-DIOXIDE POWDER

Photocatalytic oxidation of 2-hexene on TiO2, powder was investigated under a stream of oxygen gas. The main. product was 2,3-epoxyhexane wi th the chemical yield ranging fi om 65% to 83% depending on the TiO2, powders. When trans-2-hexene was used as the starting material, the ep oxide was also trans. On the other hand, cis epoxide was the chief pro duct from cis-2-hexene. From mixed 2-hexene (trans/cis = 1.7), larger amounts of trans epoxide were obtained than cis-epoxide in the initial period of the reaction, indicating that trans-2-hexene is more reacti ve than the cis isomer on the photocatalyst.