FORMATION OF METAL-OXYGEN CHAIN STRUCTURES BY BRIDGING DICHROMATE ANDCOORDINATION-COMPOUNDS - [MLNCR2O7]INFINITY (MLN=CU2+(BIPY), NI2+(EN)(2), AND NI2+(BIPY)(2))

Authors
HAYASHI Y MANO H UEHARA A
Citation
Y. Hayashi et al., FORMATION OF METAL-OXYGEN CHAIN STRUCTURES BY BRIDGING DICHROMATE ANDCOORDINATION-COMPOUNDS - [MLNCR2O7]INFINITY (MLN=CU2+(BIPY), NI2+(EN)(2), AND NI2+(BIPY)(2)), Chemistry Letters, (9), 1998, pp. 899-900
Citations number
12
Categorie Soggetti
Chemistry
Journal title
Chemistry Letters → ACNP
ISSN journal
03667022
Issue
9
Year of publication
1998
Pages
899 - 900
Database
ISI
SICI code
0366-7022(1998):9<899:FOMCSB>2.0.ZU;2-G
Abstract
Metal-oxygen linear chain compounds, [Cu(bipy)Cr2O7](infinity) (1) (bi py = 2,2'-bipyridine), [Ni(en)(2)Cr2O2](infinity) (2) (en = ethylenedi amine), and [{Ni(bipy)(2)Cr2O7}(CH3CN)](infinity) (3) have been prepar ed and characterized. X-ray structural analyses of 1 to 3 revealed thr ee chain structures: parallel in 1, layers of chains which criss-cross in 2, and helical in 3.