A NOVEL DISCRETE D-F HETEROBINUCLEAR COMPLEX DESIGNED FROM TETRAHEDRALLY DISTORTED [CU(SALABZA)] (H(2)SALABZA, N,N'-BIS(SALICYLIDENE)-2-AMINOBENZYLAMINE) AND [GD(HFAC)(3)]

Authors
SASAKI M HORIUCHI H KUMAGAI M SAKAMOTO M SAKIYAMA H NISHIDA Y SADAOKA Y OHBA M OKAWA H
Citation
M. Sasaki et al., A NOVEL DISCRETE D-F HETEROBINUCLEAR COMPLEX DESIGNED FROM TETRAHEDRALLY DISTORTED [CU(SALABZA)] (H(2)SALABZA, N,N'-BIS(SALICYLIDENE)-2-AMINOBENZYLAMINE) AND [GD(HFAC)(3)], Chemistry Letters, (9), 1998, pp. 911-912
Citations number
9
Categorie Soggetti
Chemistry
Journal title
Chemistry Letters → ACNP
ISSN journal
03667022
Issue
9
Year of publication
1998
Pages
911 - 912
Database
ISI
SICI code
0366-7022(1998):9<911:ANDDHC>2.0.ZU;2-W
Abstract
Binuclear Cu(II)-Gd(III) complex, [Cu(salabza)Gd(hfac)(3)], was synthe sized by the combination of a tetrahedrally distorted Cu(II) complex, [Cu(salabza)] with [Gd(hfac)(3)]. 2H(2)O, where H(2)salabza and Hhfac denote N,N'-bis(salicylidene)-2-aminobenzylamine and 1,1,1,5,5,5-hexaf luoroacetylacetone, respectively. Structural analysis revealed that th e complex has the long intermolecular metal-metal distances enough to be regarded as a discrete one.