TOWARD SYNTHESIS OF NOVEL C-GLYCOPROTEIN FROM HUMAN RNASE - UNEXPECTED STEREOCHEMISTRY OF EPOXIDE OPENING REACTION BY ORGANOLITHIUM REAGENTS IN THE PRESENCE OF LEWIS-ACID

Authors
MANABE S ITO Y OGAWA T
Citation
S. Manabe et al., TOWARD SYNTHESIS OF NOVEL C-GLYCOPROTEIN FROM HUMAN RNASE - UNEXPECTED STEREOCHEMISTRY OF EPOXIDE OPENING REACTION BY ORGANOLITHIUM REAGENTS IN THE PRESENCE OF LEWIS-ACID, Chemistry Letters, (9), 1998, pp. 919-920
Citations number
20
Categorie Soggetti
Chemistry
Journal title
Chemistry Letters → ACNP
ISSN journal
03667022
Issue
9
Year of publication
1998
Pages
919 - 920
Database
ISI
SICI code
0366-7022(1998):9<919:TSONCF>2.0.ZU;2-J
Abstract
A nucleophilic attack reaction to 1,2-anhydro-beta-D-mannno-pyranose b y indole derived organolithium reagents in the presence of BF3. OEt2 a fforded isomers of C-aryl glycoside corresponds to the basic skeleton of C-linked mannnosyl tryptophan, which is recently identified in huma n RNase.