TRIBENZO-1,4,5,8,9,12-HEXATHIATRIPHENYLENE DICATION AND DIBENZO-1,4,5,8-TETRATHIAPHENANTHRENE DICATION

Authors
NAKAI T KOZAKI M SATO K SHIOMI D TAKUI T ITOH K OKADA K
Citation
T. Nakai et al., TRIBENZO-1,4,5,8,9,12-HEXATHIATRIPHENYLENE DICATION AND DIBENZO-1,4,5,8-TETRATHIAPHENANTHRENE DICATION, Chemistry Letters, (9), 1998, pp. 933-934
Citations number
17
Categorie Soggetti
Chemistry
Journal title
Chemistry Letters → ACNP
ISSN journal
03667022
Issue
9
Year of publication
1998
Pages
933 - 934
Database
ISI
SICI code
0366-7022(1998):9<933:TDAD>2.0.ZU;2-H
Abstract
Tribenzo-1,4,5,8,9,12-hexathiatriphenylene dication (1(2+)) and dibenz o-1,4,5,8-tetrathiaphenanthrene dication (2(2+)) were generated in con centrated sulfuric acid. Their zero-field splitting parameters were de termined as D = 0.012 cm(-1), E approximate to 0.00 cm(-1) for 1(2+), and D = 0.012 cm(-1), E approximate to 0.00 cm(-1) for 2(2+). The dica tion 1(2+) was found to be a triplet in the ground state, whereas 2(2) to be a singlet ground state with the singlet-triplet energy gap of -35 +/- 2 J/mol.