A new excess Gibbs free energy/equation of state type mixing 0rule war
derived by removing the infinite pressure boundary condition imposed
Ly Wong and Sandler. The mixing rule was extensively tested in terms o
i a comprehensive data base, consisting of 52 simple nonpolar-nonpolar
, carbon dioxide containing, hydrocarbon-hydrocarbon, CFC, polar-polar
, nonpolar-polar binary and multicomponent systems. focused on the com
plete predictive capability, a comparison between the Wong-Sandler and
the mixing rule proposed was conducted. The results indicate that the
new mixing rule is in general superior to the Wong-Sandler's, and the
binary interaction parameter as required by the latter is removed, wh
ich reduces computing effort and is reliable in predictions of vapor-l
iquid equilibria rom low pressures Lo high pressures.