CRYSTAL-STRUCTURE OF [ZNH(NPME3)](4), A TETRAMERIC PHOSPHORANEIMINATOCOMPLEX OF ZINC WITH TERMINAL HYDRIDE LIGANDS

Authors
KRIEGER M NEUMULLER B DEHNICKE K
Citation
M. Krieger et al., CRYSTAL-STRUCTURE OF [ZNH(NPME3)](4), A TETRAMERIC PHOSPHORANEIMINATOCOMPLEX OF ZINC WITH TERMINAL HYDRIDE LIGANDS, Zeitschrift fur anorganische und allgemeine Chemie, 624(10), 1998, pp. 1563-1564
Citations number
10
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Zeitschrift fur anorganische und allgemeine Chemie
ISSN journal
00442313 → ACNP
Volume
624
Issue
10
Year of publication
1998
Pages
1563 - 1564
Database
ISI
SICI code
0044-2313(1998)624:10<1563:CO[ATP>2.0.ZU;2-D
Abstract
The crystal structure of the title compound, which crystallizes as [Zn H(NPMe3)](4). 4THF forming colourless, very reactive blocks, obtained by recrystallization from toluene, reveals discrete tetrameric molecul es with heterocubane structure with almost undistorted Zn4N4 cubic ske letons. The hydride ligands assume terminal exocyclic positions with Z n-H bond lengths of 150 pm in average.