PREPARATION AND SPECTROSCOPIC CHARACTERIZATION OF PERFLUORO(ISOPROPYL)-TRIFLUOROACETYLPEROXIDE (CF3)(2)C(F)OOC(O)CF3

Authors
MINKWITZ R REINEMANN S
Citation
R. Minkwitz et S. Reinemann, PREPARATION AND SPECTROSCOPIC CHARACTERIZATION OF PERFLUORO(ISOPROPYL)-TRIFLUOROACETYLPEROXIDE (CF3)(2)C(F)OOC(O)CF3, Zeitschrift fur anorganische und allgemeine Chemie, 624(10), 1998, pp. 1695-1698
Citations number
27
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Zeitschrift fur anorganische und allgemeine Chemie
ISSN journal
00442313 → ACNP
Volume
624
Issue
10
Year of publication
1998
Pages
1695 - 1698
Database
ISI
SICI code
0044-2313(1998)624:10<1695:PASCOP>2.0.ZU;2-1
Abstract
The reaction of perfluoroacetone (CF3)(2)CO with OF2 in a ratio 2:1 yi elds Perfluoro (isopropyl)-trifluoroacetylperoxide (CF3)(2)C(F)OOC(O)C F3. The reaction only occurs under CsF-catalysis. (CF3)(2)C(F)OOC(O)CF 3 is characterized by vibrational, nmr and mass spectra. Using an exce ss of OF2 does not give any stable product.