FINAL-SOLUTION ON THE LONG-STANDING STRUCTURAL ARGUMENTS ON THE C-3 STEREOCHEMISTRIES OF 3 GLUCOINDOLE ALKALOIDS - PALICOSIDE, DOLICHANTOSIDE, AND ISODOLICHANTOSIDE - THROUGH CHEMICAL CONVERSIONS AND SPECTROSCOPIC STUDIES

Authors
OHMORI O KUMAZAWA K HOSHINO H SUZUKI T MORISHIMA Y KOHNO H KITAJIMA M SAKAI S TAKAYAMA H AIMI N
Citation
O. Ohmori et al., FINAL-SOLUTION ON THE LONG-STANDING STRUCTURAL ARGUMENTS ON THE C-3 STEREOCHEMISTRIES OF 3 GLUCOINDOLE ALKALOIDS - PALICOSIDE, DOLICHANTOSIDE, AND ISODOLICHANTOSIDE - THROUGH CHEMICAL CONVERSIONS AND SPECTROSCOPIC STUDIES, Tetrahedron letters, 39(42), 1998, pp. 7737-7740
Citations number
18
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
39
Issue
42
Year of publication
1998
Pages
7737 - 7740
Database
ISI
SICI code
0040-4039(1998)39:42<7737:FOTLSA>2.0.ZU;2-T
Abstract
Three natural strictosidine/vincoside-class glucoindole alkaloids have been chemically correlated with strictosidinic acid possessing a rigo rously established stereostructure. The C-3 stereochemistry of palicos ide, dolichantoside, and isodolichantoside has been firmly proved to b e (S), (S), and (R), respectively. (C) 1998 Elsevier Science Ltd. All rights reserved.