SYNTHESIS AND CHARACTERIZATION OF 0,10-TETRAMETHYL-1,5,8,12-TETRAAZACYCLOTETRADECANE - A NEW ROUTE TO MACROCYCLIC POLYAMIDES AND POLYAMINES

Authors
SIRI O ROYAL G TABARD A GUILARD R HUCH V VEITH M
Citation
O. Siri et al., SYNTHESIS AND CHARACTERIZATION OF 0,10-TETRAMETHYL-1,5,8,12-TETRAAZACYCLOTETRADECANE - A NEW ROUTE TO MACROCYCLIC POLYAMIDES AND POLYAMINES, Comptes rendus de l'Academie des sciences. Serie IIc, Chimie, 1(9), 1998, pp. 557-560
Citations number
9
Categorie Soggetti
Chemistry
Journal title
Comptes rendus de l'Academie des sciences. Serie IIc, Chimie → ACNP
ISSN journal
13871609
Volume
1
Issue
9
Year of publication
1998
Pages
557 - 560
Database
ISI
SICI code
1387-1609(1998)1:9<557:SACO0>2.0.ZU;2-C
Abstract
The 1:1 and 2:2 cyclization reactions were simultaneously observed by addition of diethyl oxalate on 3,3,10,10-tetramethyl-1,5,8,12-tetraaza dodecane. The resulting 1:1 cyclisation product was fully characterize d by spectroscopy and X-ray diffraction study. The reduction of this c ompound gives the 0,10-tetramethyl-1,5,8,12-tetraazacyclotetradecane w ith a high yield. (C) Academie des sciences/Elsevier, Paris.