DISCRETENESS EFFECTS ON THE FRONT PROPAGATION IN THE A-]2A REACTION IN 3 DIMENSIONS(B)

Citation
J. Mai et al., DISCRETENESS EFFECTS ON THE FRONT PROPAGATION IN THE A-]2A REACTION IN 3 DIMENSIONS(B), Europhysics letters (Print), 44(1), 1998, pp. 7-12
Citations number
21
Categorie Soggetti
Physics
Journal title
ISSN journal
02955075
Volume
44
Issue
1
Year of publication
1998
Pages
7 - 12
Database
ISI
SICI code
0295-5075(1998)44:1<7:DEOTFP>2.0.ZU;2-N
Abstract
We consider numerically the front propagation in a three-dimensional, diffusion-controlled A + B --> 2A autocatalytic reaction. We show that the interplay between local and global ordering phenomena strongly af fects the reaction kinetics, and that it leads to the breakdown of the classical continuous scheme (described by the Fisher equation) even a t quite small concentrations of reactants. Discreteness aspects lead t o considerable deviations of the simulated behavior of chemical fronts from the continuous scheme predictions, especially in what the fronts ' structure and their propagation velocities are concerned.