We have obtained a high quality ROSAT PSPC spectrum of the bright O4 f
star zeta Pup. Allowing for the wind X-ray opacity, as computed from
detailed non-LTE stellar wind models of zeta Pup, and under the assump
tion that the X-rays arise from shocks distributed throughout the wind
, we have been able to match the observed X-ray spectrum (0.1 to 2.5ke
V). The best model fit is obtained when He++ recombines to He+ in the
outer regions of the stellar wind, as predicted by recent detailed coo
l wind model calculations. With a single temperature plasma, the best
model fit indicates a temperature of log T(s)(K) = 6.5 to 6.6 correspo
nding to shock velocities of around 500 km s-1. A 2 temperature plasma
yields a significantly improved fit, and indicates temperatures of lo
g T(s)(K) = 6.2 and 6.7 for the 2 components. The hotter component acc
ounts for 55% of the intrinsic (75% of the observed) X-ray flux. Due t
o absorption by the stellar wind, and to a minor extent stellar occult
ation, less than 5% of the total emitted X-ray flux escapes the star.
The models require significant X-ray emission (particularly at energie
s less than 0.5 keV) from large radii (r > 100R). In models without r
ecombination, the fits, even with a 2 temperature plasma, are unaccept
able. A significant K shell absorption is predicted by these models, b
ut is definitely not present in the observational data. The analysis s
uggests that the X-ray flux provides an invaluable diagnostic of the i
onization of helium in the stellar wind of stars with low reddening.