ENANTIOSELECTIVE SYNTHESIS OF JUVENILE HORMONE-III IN 3 STEPS FROM METHYL FARNESOATE

Authors
CRISPINO GA SHARPLESS KB
Citation
Ga. Crispino et Kb. Sharpless, ENANTIOSELECTIVE SYNTHESIS OF JUVENILE HORMONE-III IN 3 STEPS FROM METHYL FARNESOATE, Synthesis, (8), 1993, pp. 777-779
Citations number
10
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synthesis → ACNP
ISSN journal
00397881
Issue
8
Year of publication
1993
Pages
777 - 779
Database
ISI
SICI code
0039-7881(1993):8<777:ESOJHI>2.0.ZU;2-C
Abstract
The asymmetric dihydroxylation of methyl farnesoate resulted in regios elective dihydroxylation of the 10, 11 olefin to give the (10S)- and , 11-dihydroxy-3,7,11-trimethyl-2,6-dodecadienoates in high ee. These di ols were converted to juvenile hormone III and its enantiomer.