A SYNTHESIS OF ALLYLIC DIPHENYLPHOSPHINIC ESTERS

Authors
MCCALLUM JS LIEBESKIND LS
Citation
Js. Mccallum et Ls. Liebeskind, A SYNTHESIS OF ALLYLIC DIPHENYLPHOSPHINIC ESTERS, Synthesis, (8), 1993, pp. 819-823
Citations number
18
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synthesis → ACNP
ISSN journal
00397881
Issue
8
Year of publication
1993
Pages
819 - 823
Database
ISI
SICI code
0039-7881(1993):8<819:ASOADE>2.0.ZU;2-0
Abstract
The preparation of diphenylphosphinate esters of allylic alcohols is r eported. Addition of allylic alcohols to the imidazolinium salt prepar ed in situ from diphenylphosphinic chloride and imidazole or to 1-(dip henylphosphinoyl)imidazole produces the corresponding diphenylphosphin ate esters in good to excellent yields.