1,2-ASYMMETRIC INDUCTION IN REACTIONS BETWEEN ORGANOMETALLIC REAGENTSAND CHIRAL BETA-HYDROXYALDEHYDE DERIVATIVES - DETERMINATION BY H-1-NMR SPECTROSCOPY OF THE STEREOCHEMISTRY VIA 1,3-DIOXANES
D. Dekermadec et al., 1,2-ASYMMETRIC INDUCTION IN REACTIONS BETWEEN ORGANOMETALLIC REAGENTSAND CHIRAL BETA-HYDROXYALDEHYDE DERIVATIVES - DETERMINATION BY H-1-NMR SPECTROSCOPY OF THE STEREOCHEMISTRY VIA 1,3-DIOXANES, Journal of chemical research. Synopses, (8), 1993, pp. 328-329
Coupling constants in 1,3-dioxane derivatives afford the stereochemist
ry of the diastereoisomers formed by addition of organometallic reagen
ts to chiral aldehydes.