PHOTOLYSIS OF TERT-BUTYL(MESITYL)PHOSPHINIC AZIDE - INFLUENCE OF DIMETHYL SULFIDE ON INTRAMOLECULAR NITRENE INSERTION AND CURTIUS-LIKE REARRANGEMENT

Authors
HARGER MJP
Citation
Mjp. Harger, PHOTOLYSIS OF TERT-BUTYL(MESITYL)PHOSPHINIC AZIDE - INFLUENCE OF DIMETHYL SULFIDE ON INTRAMOLECULAR NITRENE INSERTION AND CURTIUS-LIKE REARRANGEMENT, Journal of chemical research. Synopses, (8), 1993, pp. 334-335
Citations number
11
Categorie Soggetti
Chemistry
Journal title
Journal of chemical research. Synopses → ACNP
ISSN journal
03082342
Issue
8
Year of publication
1993
Pages
334 - 335
Database
ISI
SICI code
0308-2342(1993):8<334:POTA-I>2.0.ZU;2-Q
Abstract
When tert-butyl(mesityl)phosphinic azide (5b) is photolysed in the pre sence of Me2S the sulfilimine 9 is formed at the expense of intramolec ular nitrene insertion rather than Curtius-like rearrangement.