Various solid state spectroscopy techniques applied to zirconia (Y-TZP
) ceramic femoral ball heads for total hip replacement showed that the
ir pronounced colour change, after gamma sterilisation, from off white
to a purplish grey shade, can be related to two electronic transition
s at local defects in the crystal lattice. From the experimental resul
ts it can be safely concluded that the colour changes are not caused b
y elevated impurity levels and thus do not compromise the required mec
hanical or chemical performance of the material.