Photoluminescence (PL) measurements have been carried out to investiga
te the hydrogenation and annealing effects of unintentionally doped n-
type GaN epitaxial layers grown on sapphire substrates by plasma-assis
ted molecular beam epitaxy. When the as-grown GaN/sapphire heterostruc
ture is annealed at 800 degrees C. a new peak corresponding to the neu
tral donor-bound excitons appears. After hydrogenation, the yellow pea
k appeared for the as-grown GaN/sapphire heterostructure annealed at 8
00 degrees C disappears. When the hydrogenated GaN/sapphire heterostru
cture is annealed at 950 degrees C, three peaks appears. These results
indicate that the crystallinity of the unintentionally doped n-type G
aN epilayers grown on sapphire substrates is improved by hydrogenation
and annealing.