The basic mechanism of electron emissivity of a Zr-Si/W(100) surface,
which has attracted much attention as a thermal field emitter for prac
tical use, was studied by Auger electron spectroscopy, ion scattering
spectroscopy and work function measurements. The results show that the
topmost atomic layer consists of Zr and Si at operating conditions (s
imilar to 1300 K, 10(-9) Torr), the work function of which is slightly
reduced by an order of half an eV from that of a clean W(100) surface
.