EXTRACTION OF MOLECULAR-IODINE WITH SOLUTIONS OF TRIBUTYL-PHOSPHATE IN RED-4

Citation
Op. Anisimov et al., EXTRACTION OF MOLECULAR-IODINE WITH SOLUTIONS OF TRIBUTYL-PHOSPHATE IN RED-4, Radiochemistry, 40(4), 1998, pp. 338-341
Citations number
7
Categorie Soggetti
Chemistry Analytical","Chemistry Inorganic & Nuclear
Journal title
ISSN journal
10663622
Volume
40
Issue
4
Year of publication
1998
Pages
338 - 341
Database
ISI
SICI code
1066-3622(1998)40:4<338:EOMWSO>2.0.ZU;2-N
Abstract
A study was made of distribution of molecular iodine between aqueous s olutions and 30% TBP solution in RED-4. In the studied range of the vo lume ratios between the organic and aqueous phases and the initial con centration of iodine the distribution coefficient of iodine varies fro m 500 to 1500, The regression equation was formulated which adequately describes the dependence of the It distribution coefficient on the vo lume ratio between the organic and aqueous phase, the volume content o f TBP in the extractant, and the iodine concentration in the initial s olution. The distribution coefficient has no maximum within the range of variation of the principal factors and steeply increases with incre asing TBP concentration. The 15-20% TBP solutions in RED-4 were found to be the optimal in extraction of iodine.