RADIATION-CHEMICAL RESISTANCE OF ANION-EXCHANGERS AND SAFETY OF SORPTION PROCESSES IN NITRIC-ACID SOLUTIONS - I - CAUSES OF FAILURE OF THE SORPTION COLUMN OF THE UNIT FOR PRODUCTION OF PU-238 AT THE RADIOISOTOPE PLANT, MAYAK-PRODUCTION-ASSOCIATION

Citation
Sa. Bartenev et al., RADIATION-CHEMICAL RESISTANCE OF ANION-EXCHANGERS AND SAFETY OF SORPTION PROCESSES IN NITRIC-ACID SOLUTIONS - I - CAUSES OF FAILURE OF THE SORPTION COLUMN OF THE UNIT FOR PRODUCTION OF PU-238 AT THE RADIOISOTOPE PLANT, MAYAK-PRODUCTION-ASSOCIATION, Radiochemistry, 40(4), 1998, pp. 391-394
Citations number
1
Categorie Soggetti
Chemistry Analytical","Chemistry Inorganic & Nuclear
Journal title
ISSN journal
10663622
Volume
40
Issue
4
Year of publication
1998
Pages
391 - 394
Database
ISI
SICI code
1066-3622(1998)40:4<391:RROAAS>2.0.ZU;2-N
Abstract
The course and causes of the emergency that took place in 1993 on the sorption unit for production of ultrapure (PU)-P-238 at the Radioisoto pe Plant, Mayak Production Association, are discussed. The thermal cal culations and thermogravimetric studies of anion exchanger samples (no nirradiated, irradiated, and saturated with plutonium) showed that the emergency was due to draining of the liquid from the column and progr essing thermochemical degradation of VP-1Ap anion exchanger.