A simple way of understanding the nonadditivity of van der Waals dispersion forces

Citation
C. Farina et al., A simple way of understanding the nonadditivity of van der Waals dispersion forces, AM J PHYS, 67(4), 1999, pp. 344-349
Citations number
16
Categorie Soggetti
Physics
Journal title
AMERICAN JOURNAL OF PHYSICS
ISSN journal
00029505 → ACNP
Volume
67
Issue
4
Year of publication
1999
Pages
344 - 349
Database
ISI
SICI code
0002-9505(199904)67:4<344:ASWOUT>2.0.ZU;2-R
Abstract
Using a semiclassical model for three interacting fluctuating dipoles we in troduce a simple scenario in which the nonadditivity of the van der Waals d ispersion forces arises in a very transparent way. For simplicity, we illus trate our model in the case of nonretarded dispersion forces. The argument can be straightforwardly generalized to the case of N interacting fluctuati ng dipoles. For pedagogical reasons, we also give a brief review of some ba sic points concerning van der Waals forces. (C) 1999 American Association o f Physics Teachers.