New potentiometric gas-gap sensor

Citation
Ov. Yagodina et Eb. Nikolskaya, New potentiometric gas-gap sensor, ANALYT CHIM, 385(1-3), 1999, pp. 137-141
Citations number
15
Categorie Soggetti
Spectroscopy /Instrumentation/Analytical Sciences
Journal title
ANALYTICA CHIMICA ACTA
ISSN journal
00032670 → ACNP
Volume
385
Issue
1-3
Year of publication
1999
Pages
137 - 141
Database
ISI
SICI code
0003-2670(19990405)385:1-3<137:NPGS>2.0.ZU;2-S
Abstract
A new gas-gap sensor for the determination of ammonia on the base of a pH-m etric electrode is described. It has been established that the equality of the ionic strength and temperature of the sample and the electrode solution is no longer necessary. This allows to reduce the limit of detection for a mmonia to 5x10(-10) M, to vary the measurable ammonia concentration range f rom 1x10(-9)-1x10(-5) M up to 1x10(-7)-1x10(-3) M and to reduce the respons e time to several minutes. (C) 1999 Elsevier Science B.V. All rights reserv ed.