G. Franchini et al., Density and excess molar volume values of binary mixtures of 2-chloroethanol plus 1,2-ethanediol, ANN CHIM, 89(1-2), 1999, pp. 157-166
Densities (rho) of the 2-chloroethanol + 1,2-ethanediol binary solvent syst
em are presented at 19 temperatures in the -10 less than or equal to t/degr
ees C less than or equal to +80 range. The measured values have been used t
o test some empirical equations of the type rho=rho(t), rho=rho(X-1) and rh
o=rho(t,X-1), in order to provide useful interpolation procedures to obtain
calculated values corresponding to the experimental data gaps. From the pr
imary data, the excess molar volumes (V-E ) have been calculated. The sign
and magnitude of this quantity have been discussed in terms of the type and
nature of binary interactions. Furthermore, the derived quantities have fi
tted the Redlich-Kister equation with very good accuracy.