Differential pulse polarography and electron spin resonance spectroscopy of nitroxyl free radicals used as ESR-spin probes

Authors
Kroll, C Schwarz, KH Surmann, P Borchert, HH
Citation
C. Kroll et al., Differential pulse polarography and electron spin resonance spectroscopy of nitroxyl free radicals used as ESR-spin probes, BIOELECTR B, 48(1), 1999, pp. 233-236
Citations number
19
Categorie Soggetti
Biochemistry & Biophysics
Journal title
BIOELECTROCHEMISTRY AND BIOENERGETICS
ISSN journal
03024598 → ACNP
Volume
48
Issue
1
Year of publication
1999
Pages
233 - 236
Database
ISI
SICI code
0302-4598(199902)48:1<233:DPPAES>2.0.ZU;2-M
Abstract
Differential pulse polarography (DPP) and electron spin resonance (ESR) wer e used to study the influence of substituents and of the pH of the medium o n DPP peak potentials (electrochemical reduction) resp. k(reduction) (chemi cal reduction) of nitroxyl free radicals. The DPP peak potentials can be us ed to select the appropriate nitroxide spin label for relevant biochemical and biophysical applications. (C) 1999 Elsevier Science S.A. All rights res erved.