First catalysis by corrole metal complexes: epoxidation, hydroxylation, and cyclopropanation

Authors
Gross, Z Simkhovich, L Galili, N
Citation
Z. Gross et al., First catalysis by corrole metal complexes: epoxidation, hydroxylation, and cyclopropanation, CHEM COMMUN, (7), 1999, pp. 599-600
Citations number
24
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
7
Year of publication
1999
Pages
599 - 600
Database
ISI
SICI code
1359-7345(19990407):7<599:FCBCMC>2.0.ZU;2-E
Abstract
The first ever application of corroles shows that their metal complexes are good catalysts, almost as potent as the corresponding metalloporphyrins in the oxygenation of hydrocarbons by iodosylbenzene and superior for the cyc lopropanation of olefins by carbenoids.