In this study the mechanism of luminescence of aqueous solution surfactants
has been considered. It is shown that at the point of micellization the in
tensity of luminescence non-linearity depends on aggregate size. Experiment
al results on the action of laser light on aqueous solutions of sodium octy
lbenzene sulphonate confirm that in the process of photoionization active p
arts are taken by not only donor electrons solubilized in micelles but also
electrons of surfactant molecules. (C) 1999 Elsevier Science B.V. All righ
ts reserved.