RAPID CHARACTERIZATION OF RHODIUM DIHYDRIDES BY NUCLEAR-MAGNETIC-RESONANCE SPECTROSCOPY USING INDIRECT 2-DIMENSIONAL METHODS AND PARA-HYDROGEN

Authors
DUCKETT SB BARLOW GK PARTRIDGE MG MESSERLE BA
Citation
Sb. Duckett et al., RAPID CHARACTERIZATION OF RHODIUM DIHYDRIDES BY NUCLEAR-MAGNETIC-RESONANCE SPECTROSCOPY USING INDIRECT 2-DIMENSIONAL METHODS AND PARA-HYDROGEN, Journal of the Chemical Society. Dalton transactions, (20), 1995, pp. 3427-3429
Citations number
16
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of the Chemical Society. Dalton transactions → ACNP
ISSN journal
03009246
Issue
20
Year of publication
1995
Pages
3427 - 3429
Database
ISI
SICI code
0300-9246(1995):20<3427:RCORDB>2.0.ZU;2-9
Abstract
When [RhH2(PMe(3))(3)Cl], incorporating chemically inequivalent hydrid es, and [RhH2(PMe(3))(4)]Cl, containing magnetically inequivalent hydr ides.,were generated using para-enriched hydrogen, their H-1-Rh-103 an d H-1-P-31 two-dimensional NMR spectra were quickly obtained from < 1 mg of complex with and without the aid of pulsed field gradients.