A section at Kizildere in the Misis-Adana Basin of Turkey reveals rela
tions among mature massive caliche (calcrete) and paleosolic immature
caliche and the Tertiary clay (the Handere Formation) and colluvial de
posits. It also defines a gradational sequence from unweathered Tertia
ry clay deposits to massive caliches. From older to younger, the secti
on comprises: Tertiary clays, paleosolic caliche, colluvial material,
massive caliche, and lenticular caliche. The two massive caliche beds
have similar assemblages of carbonate minerals, whereas the paleosolic
caliche contains more clay minerals and most probably represents an e
arlier stage of massive caliche formation. The variability of types of
calcite, the quantity and crystallisation state of palygroskite, and
the presence of kaolinite and degraded smectite all support the view t
hat the massive caliche is the end product of a degradation sequence f
rom the Tertiary clay deposit to paleosolic caliche, and the lenticula
r caliche is the well-known petrocalcic horizon.