Luminescence properties and crystal structures of dicyano(diimine)platinum(II) complexes controlled by Pt center dot center dot center dot Pt and pi-pi interactions

Authors
Kato, M Kosuge, C Morii, K Ahn, JS Kitagawa, H Mitani, T Matsushita, M Kato, T Yano, S Kimura, M
Citation
M. Kato et al., Luminescence properties and crystal structures of dicyano(diimine)platinum(II) complexes controlled by Pt center dot center dot center dot Pt and pi-pi interactions, INORG CHEM, 38(7), 1999, pp. 1638
Citations number
17
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANIC CHEMISTRY
ISSN journal
00201669 → ACNP
Volume
38
Issue
7
Year of publication
1999
Database
ISI
SICI code
0020-1669(19990405)38:7<1638:LPACSO>2.0.ZU;2-2
Abstract
Orange-red crystals of [Pt(CN)(2)(bpy)] (bpy = 2,2' - bipyridine) and [Pt(C N)(2)(i-biq)] (i-biq = 3,3'-biisoquinoline) show completely different tempe rature-dependence of emission behavior which has been explained in terms of the characteristic change of each crystal structure based on the platinum- platinum and ligand pi-pi interactions.