Asymmetric benzothiophene condensation facilitated by platinum(II). The distinct roles of platinum(II) and palladium(II)

Authors
Teixidor, F Angles, P Vinas, C Kivekas, R Sillanpaa, R
Citation
F. Teixidor et al., Asymmetric benzothiophene condensation facilitated by platinum(II). The distinct roles of platinum(II) and palladium(II), INORG CHEM, 38(7), 1999, pp. 1642
Citations number
13
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANIC CHEMISTRY
ISSN journal
00201669 → ACNP
Volume
38
Issue
7
Year of publication
1999
Database
ISI
SICI code
0020-1669(19990405)38:7<1642:ABCFBP>2.0.ZU;2-O
Abstract
The ligand 2,6-bis(o-cyanophenylthiomethyl)pyridine reacts with Pt(II) and Pd(II) to produce a complex with rearrangent of the original ligand: a benz othiophene condensation on one arm is obtained in the case of Pt(II) but in the case of Pd(II) the two arms of the ligand have reacted to produce a to tally aromatic system.