A neutral molecule of I-2 as a bridge for dimerization of iodine iron(III)phthalocyanine

Authors
Janczak, J Kubiak, R Hahn, F
Citation
J. Janczak et al., A neutral molecule of I-2 as a bridge for dimerization of iodine iron(III)phthalocyanine, INORG CHIM, 287(1), 1999, pp. 101-104
Citations number
48
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANICA CHIMICA ACTA
ISSN journal
00201693 → ACNP
Volume
287
Issue
1
Year of publication
1999
Pages
101 - 104
Database
ISI
SICI code
0020-1693(19990402)287:1<101:ANMOIA>2.0.ZU;2-9
Abstract
The compound (C32H16N8FeI)(2)I-2 is formed in the reaction of liquid 1,2-di cyanobenzene in the presence of pure powder of iron and I-2. Raman spectra and X-ray crystal structure analysis clearly shows that neutral diiodine mo lecules exist as a bridge in the crystal structure. The Fe atom is five-coo rdinate, having distorted square-pyramidal geometry. It lies 0.258(2) Angst rom above the plane defined by the four N-isoindole atoms. (C) 1999 Elsevie r Science S.A. All rights reserved.