SEPARATION AND CHARACTERIZATION OF DIASTEREOMERIC (ETA(4)-DIENE)FE(CO)3 COMPLEXES CONTAINING CHIRAL AMIDE GROUPS

Authors
NAKANISHI S YAMAMOTO H OTSUJI Y NAKAZUMI H
Citation
S. Nakanishi et al., SEPARATION AND CHARACTERIZATION OF DIASTEREOMERIC (ETA(4)-DIENE)FE(CO)3 COMPLEXES CONTAINING CHIRAL AMIDE GROUPS, Tetrahedron : asymmetry, 4(9), 1993, pp. 1969-1972
Citations number
5
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear","Chemistry Physical
Journal title
Tetrahedron : asymmetry → ACNP
ISSN journal
09574166
Volume
4
Issue
9
Year of publication
1993
Pages
1969 - 1972
Database
ISI
SICI code
0957-4166(1993)4:9<1969:SACOD(>2.0.ZU;2-S
Abstract
Diastereomeric (eta4-N-substituted-2,4-hexadienamide)Fe(CO)3 complexes having chiral amide groups are separated and characterized. Among the complexes, the amide complexes derived from (3R)- and (3S)-3-amino-he xahydro-2H-azepin-2-one are die most easily separated by fractional cr ystallization and column chromatography.