FORMATION AND STABILIZATION OF THE HEXA-CYCLOPENTADIENE ADDUCT OF C-60

Authors
MEIDINE MF ROERS R LANGLEY GJ AVENT AG DARWISH AD FIRTH S KROTO HW TAYLOR R WALTON DRM
Citation
Mf. Meidine et al., FORMATION AND STABILIZATION OF THE HEXA-CYCLOPENTADIENE ADDUCT OF C-60, Journal of the Chemical Society, Chemical Communications, (17), 1993, pp. 1342-1344
Citations number
12
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
17
Year of publication
1993
Pages
1342 - 1344
Database
ISI
SICI code
0022-4936(1993):17<1342:FASOTH>2.0.ZU;2-2
Abstract
Up to 6 equiv. of cyclopentadiene react with C60, and the resulting Di els-Alder adducts can be stabilised towards degradation during mass sp ectrometric analysis by hydrogenation of the pendant bicyclopentene mo ieties; stabilisation can also be affected by bromination.