Synthesis of ring-substituted bis-eta(5)-cyclopentadienyl derivatives of the group IV elements containing the bicyclic ligands eta(5)-C5H3(1,2-CH2-)(n), n = 4, 5, or 6

Authors
Polo, E Bellabarba, RM Prini, G Traverso, O Green, MLH
Citation
E. Polo et al., Synthesis of ring-substituted bis-eta(5)-cyclopentadienyl derivatives of the group IV elements containing the bicyclic ligands eta(5)-C5H3(1,2-CH2-)(n), n = 4, 5, or 6, J ORGMET CH, 577(2), 1999, pp. 211-218
Citations number
34
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
JOURNAL OF ORGANOMETALLIC CHEMISTRY
ISSN journal
0022328X → ACNP
Volume
577
Issue
2
Year of publication
1999
Pages
211 - 218
Database
ISI
SICI code
0022-328X(19990401)577:2<211:SORBDO>2.0.ZU;2-B
Abstract
The synthesis of unsubstituted and substituted bicyclic eta(5)-cyclopentadi enyl ligands and their Group IV metal complexes [M{eta(5)-C5H3(1,2-CH2-)(n) }(2)Cl-2], where n = 4, 5, 6 and M = Ti, Zr, Hf, is reported. An example of an ansa-bridged zirconium analogue is also described. (C) 1999 Elsevier Sc ience S.A. All rights reserved.