Synthesis, structure and properties of 1,2-dihydroxy-tetramethyldisilane

Authors
Prasse, M Reinke, H Wendler, C Kelling, H
Citation
M. Prasse et al., Synthesis, structure and properties of 1,2-dihydroxy-tetramethyldisilane, J ORGMET CH, 577(2), 1999, pp. 342-345
Citations number
15
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
JOURNAL OF ORGANOMETALLIC CHEMISTRY
ISSN journal
0022328X → ACNP
Volume
577
Issue
2
Year of publication
1999
Pages
342 - 345
Database
ISI
SICI code
0022-328X(19990401)577:2<342:SSAPO1>2.0.ZU;2-L
Abstract
1,2-Dihydroxy-tetramethyldisilane (2) has been synthesized by hydrolysis of 1,2-dichloro-tetramethyldisilane (1) and characterized by IR, NMR, MS and X-ray structure analysis. Compound 2 exists in crystal form in two differen t conformations forming a characteristic two-dimensional network by H-bondi ng. The title compound is water soluble and has a high condensation tendenc y. (C) 1999 Elsevier Science S.A. All rights reserved.