Channelled ions in a Si single crystal see a very high density quasi-free e
lectron gas and hence provide an opportunity to study e-impact ionization o
f the projectile even though the e-e interaction responsible for this is mu
ch weaker than the e-n interaction which usually dominates the process of p
rojectile ionization. The e-e interaction has been experimentally identifie
d through the observed fast increase in the impact energy dependence of the
ionization of the hydrogen-like F ions, the calculated contribution from t
he e-n interaction being impact energy independent at large impact paramete
rs. The relative variation of the measured cross sections for well-channell
ed ions is in good agreement with the convergent close-coupling theory of e
-impact ionization and existing scaling laws. In addition to the M-shell el
ectrons, participation of the Si L-shell in the ionization of the channelle
d ion is suggested.