The adsorption properties of several branched paraffins from C-4 to C-6 on
MFI type zeolite were investigated. A temperature-programmed-equilibration
method was used for this study, and the analysis of the desorption rates as
a function of temperature showed two desorption peaks. The interpretation
of this phenomenon is discussed, and it is revealed that the high-temperatu
re desorption occurs in conditions close to equilibrium while low-temperatu
re desorption is subject to diffusional limitations. Furthermore, an XRD st
udy shows that the phase transition in the crystal structure can be lowered
by 70 K when 3-methylpentane is adsorbed. This property shows that the low
-temperature desorption peak is not due to a change of symmetry in the stru
cture of the zeolite. Modeling of the high-temperature peak provided adsorp
tion isosteric enthalpy and entropy variations. These values are consistent
with literature data. For the first time, adsorption isosteric entropy var
iations of sorption are calculated for branched alkanes in silicalite-1.