Resonant magnetic tunnelling in Mn-12 2-Cl benzoate

Citation
F. Luis et al., Resonant magnetic tunnelling in Mn-12 2-Cl benzoate, NANOTECHNOL, 10(1), 1999, pp. 86-89
Citations number
20
Categorie Soggetti
Apllied Physucs/Condensed Matter/Materiales Science","Material Science & Engineering
Journal title
NANOTECHNOLOGY
ISSN journal
09574484 → ACNP
Volume
10
Issue
1
Year of publication
1999
Pages
86 - 89
Database
ISI
SICI code
0957-4484(199903)10:1<86:RMTIM2>2.0.ZU;2-3
Abstract
We present a detailed experimental study of magnetic relaxation on it singl e crystal of Mn-12 2Cl-benzoate and compare with results obtained on a sing le crystal of Mn-12 acetate. Relaxation times obtained from a.c. susceptibi lity experiments for both samples show sharp minima at the same resonant fi elds. Although magnetic relaxation of Mn-12 2-Cl benzoate is faster at any field and temperature, activation energies in zero field are approximately equal. This is an indication that a small increase of the transverse fields magnitude (arising from dipole-dipole interactions) does not modify apprec iably tunnelling rates between spin states which are degenerate at zero fie ld. This result agrees with the predictions of a new theoretical model rece ntly developed by some of the authors.