We studied the distribution of different forms of N in very young (0-
to 7-year-old) soils from the Meirama lignite mine in northwest Spain.
Total N increased rapidly with soil age, largely in the humic acid-as
sociated fraction. Acid hydrolysis indicated that amino acid N and a h
ydrolysable unknown form of N increased with soil age. The fractionati
on reported by Bettany et al. (1980) indicated that alkali/pyrophospha
te-extractable humus increased with soil age. All these data suggest t
hat there is rapid stabilization of organic N during the first few yea
rs of evolution of these mine soils, to the extent that distribution o
f N forms in the 7-year-old soil is very similar to that in native soi
ls.