Nv. Novikov et Vs. Senashenko, Description of the (2s(2))S-1, (2s2p)P-1, (2p(2))D-1, and (1snl)L-1 (n <= 6, l <= 2) states of the helium atom by the variational method, OPT SPECTRO, 86(3), 1999, pp. 320-326
A new theoretical model and a method of calculation of the wave functions o
f the autoionization and the (1snl)L-1 states are proposed. The theory is b
ased on the method of superposition of configurations and uses an approxima
tion of basis functions by a linear combination of hydrogen-like functions
with effective charges. The resulting wave functions satisfy all the orthog
onality requirements, in the approximation ignoring the non-Coulomb part of
the He+ potential, the width of the (2s(2))S-1, (2s2p)P-1, and (2p2)D-1 re
sonances and the shift of the resonance positions owing to the interaction
with the degenerate continuum were calculated. The results of the calculati
ons agree well with the presently available experimental and theoretical da
ta.