Description of the (2s(2))S-1, (2s2p)P-1, (2p(2))D-1, and (1snl)L-1 (n <= 6, l <= 2) states of the helium atom by the variational method

Citation
Nv. Novikov et Vs. Senashenko, Description of the (2s(2))S-1, (2s2p)P-1, (2p(2))D-1, and (1snl)L-1 (n <= 6, l <= 2) states of the helium atom by the variational method, OPT SPECTRO, 86(3), 1999, pp. 320-326
Citations number
22
Categorie Soggetti
Spectroscopy /Instrumentation/Analytical Sciences
Journal title
OPTICS AND SPECTROSCOPY
ISSN journal
0030400X → ACNP
Volume
86
Issue
3
Year of publication
1999
Pages
320 - 326
Database
ISI
SICI code
0030-400X(199903)86:3<320:DOT(((>2.0.ZU;2-H
Abstract
A new theoretical model and a method of calculation of the wave functions o f the autoionization and the (1snl)L-1 states are proposed. The theory is b ased on the method of superposition of configurations and uses an approxima tion of basis functions by a linear combination of hydrogen-like functions with effective charges. The resulting wave functions satisfy all the orthog onality requirements, in the approximation ignoring the non-Coulomb part of the He+ potential, the width of the (2s(2))S-1, (2s2p)P-1, and (2p2)D-1 re sonances and the shift of the resonance positions owing to the interaction with the degenerate continuum were calculated. The results of the calculati ons agree well with the presently available experimental and theoretical da ta.