The NEXAFS regions of Cl-2 near the 2p and 1s core thresholds have been the
oretically considered. The electron excitations below the ionization limit
have been treated with a highly correlated ab initio method (QDPT-CI). The
position of doubly excited states above Is ionization has also been conside
red at the CI level. The region above the threshold is described with an ex
plicit continuum method, based on a LCAO formalism within the framework of
density functional theory. The results are in very good accordance with the
experiment and support detailed assignment of the spectral feature. Compar
ison of the present results with respect to previous work on HCl shows a mo
re atomic behaviour of Cl-2 with respect to HCl below edge and the opposite
in the continuum. The former is traced to the stronger chemical bond in HC
l, the second to the larger relaxation of Cl-2 in the ionic state.