Metastable eutectic, gas to solid, condensation in the FeO-Fe2O3-SiO2 system

Citation
Fjm. Rietmeijer et al., Metastable eutectic, gas to solid, condensation in the FeO-Fe2O3-SiO2 system, PCCP PHYS C, 1(7), 1999, pp. 1511-1516
Citations number
27
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
PCCP PHYSICAL CHEMISTRY CHEMICAL PHYSICS
ISSN journal
14639076 → ACNP
Volume
1
Issue
7
Year of publication
1999
Pages
1511 - 1516
Database
ISI
SICI code
1463-9076(19990401)1:7<1511:MEGTSC>2.0.ZU;2-3
Abstract
Non-equilibrium gas to solid condensation produced three distinct groupings of ferrosilica solids with compositions similar to 15, 30 and 87.5 wt.% Fe O (or, similar to 17, 33 and 97 wt.% Fe2O3). These solid compositions defin e metastable eutectic points in the FeO/Fe2O3-SiO2 binary system. The posit ion of a silica-rich metastable eutectic is sensitive to the ratio FeO : Fe 2O3 during gas-to-solid quenching. The Fe-rich metastable eutectic indicate s a two-liquid held in this revised pseudo-binary equilibrium phase diagram .