We report the first observation of intrinsic optical bistability in CsCdBr3
:1% Yb3+ and show, using site-selective spectroscopy, that only the asymmet
ric, strongly coupled Yb3+ ion-pair minority site gives rise to hysteresis
of near-infrared and cooperative up-conversion luminescence as a function o
f incident laser intensity below 15 K. [S0031-9007(99)08880-8].