Role of protons in methyl phenyl sulfide oxidation with hydrogen peroxide catalyzed by Ti(IV)-monosubstituted heteropolytungstates

Authors
Kholdeeva, OA Maksimov, GM Maksimovskaya, RI Kovaleva, LA Fedotov, MA
Citation
Oa. Kholdeeva et al., Role of protons in methyl phenyl sulfide oxidation with hydrogen peroxide catalyzed by Ti(IV)-monosubstituted heteropolytungstates, REACT KIN C, 66(2), 1999, pp. 311-317
Citations number
16
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
REACTION KINETICS AND CATALYSIS LETTERS
ISSN journal
01331736 → ACNP
Volume
66
Issue
2
Year of publication
1999
Pages
311 - 317
Database
ISI
SICI code
0133-1736(199903)66:2<311:ROPIMP>2.0.ZU;2-E
Abstract
Acid tetrabutylammonium salts of Ti(TV)-monosubstituted heteropolytungstate , PW11TiO405-, show high catalytic activity in the oxidation of methyl phen yl sulfide with hydrogen peroxide, while the corresponding tetrabutylammoni um salts containing no protons are poor catalysts for this reaction.