Montmorillonite K 10 (clay) catalyzed hydrolysis of aryl-substituted alpha,beta-difluoroallyl alcohols leading to (Z)-alpha-fluoro-beta-aryl-substituted acrylaldehydes

Authors
Funabiki, K Murata, E Fukushima, Y Matsui, M Shibata, K
Citation
K. Funabiki et al., Montmorillonite K 10 (clay) catalyzed hydrolysis of aryl-substituted alpha,beta-difluoroallyl alcohols leading to (Z)-alpha-fluoro-beta-aryl-substituted acrylaldehydes, TETRAHEDRON, 55(15), 1999, pp. 4637-4642
Citations number
43
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON
ISSN journal
00404020 → ACNP
Volume
55
Issue
15
Year of publication
1999
Pages
4637 - 4642
Database
ISI
SICI code
0040-4020(19990409)55:15<4637:MK1(CH>2.0.ZU;2-L
Abstract
Aryl-substituted alpha,beta-difluoroallyl alcohols 1 were readily hydrolyze d in the presence of a catalytic amount of montmorillonite K 10 (clay) in h exane at reflux temperature for 1 h to give the corresponding (Z)-alpha-flu oro-beta-aryl-substituted acrylaldehydes 2 in good yields. (C) 1999 Elsevie r Science Ltd. All rights reserved.