Formation and structure of [{(CH3)(3)Si}(3)C((C3H7)-C-n)In(mu-OH)]3

Authors
Walz, A Niemeyer, M Weidlein, J
Citation
A. Walz et al., Formation and structure of [{(CH3)(3)Si}(3)C((C3H7)-C-n)In(mu-OH)]3, Z ANORG A C, 625(4), 1999, pp. 547-549
Citations number
21
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
ISSN journal
00442313 → ACNP
Volume
625
Issue
4
Year of publication
1999
Pages
547 - 549
Database
ISI
SICI code
0044-2313(199904)625:4<547:FASO[>2.0.ZU;2-Z
Abstract
The title compound has been prepared in low yield by the reaction of [(TKF) (2)LiC(SiMe3)(3)](2) with humid di(n-propyl) indium bromide and purified by sublimation at 110-115 degrees C/10(-3) hPa. This organo indium hydroxe co mpound forms a trimer via In-OH-In bridges and crystallizes in the triclini c space group P (1) over bar with two trimers and one toluene molecule per unitcell. The In3O3 heterocycle has chair-, the n-propyl ligand has trans-c onformation, respectively.