Studies on polyhalides. 40. Ethyltrimethylammonium pentaiodide (EtMe3N)I-5

Authors
Loukili, R Tebbe, KF
Citation
R. Loukili et Kf. Tebbe, Studies on polyhalides. 40. Ethyltrimethylammonium pentaiodide (EtMe3N)I-5, Z ANORG A C, 625(4), 1999, pp. 650-654
Citations number
46
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
ISSN journal
00442313 → ACNP
Volume
625
Issue
4
Year of publication
1999
Pages
650 - 654
Database
ISI
SICI code
0044-2313(199904)625:4<650:SOP4EP>2.0.ZU;2-6
Abstract
(EtMe3N)I-5 has been prepared by the reaction of stoichiometric amounts of ethyltrimethylammonium iodide and iodine in methanol. It crystallizes in th e orthorhombic space group Pna2(1) with a=1011.3(1) pm, b=1255.3(2) pm, c = 1237.7(2) pm and Z = 4. The anionic iodine partial structure is composed o f puckered layers which may be derived by deforming a quadratic net with io dide ions in the knots and iodine molecules on the edges of the meshes.